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Hess's Law

▶︎  Watch it animatedinteractive step-through · ~3 min · optional

Hess's law says that because enthalpy is a state function, a reaction's ΔH depends only on the initial and final states, not the path. So you can combine known reactions — reversing one flips the sign of its ΔH, scaling one multiplies its ΔH — until they add up to the target reaction, then sum the ΔH values.

UNIT 6 TOPIC 6.9 • HESS'S LAW HESS'S LAW STATE FUNCTION ΔH depends only on the initial and final states — not on the path taken. A B C ΔH₁ ΔH₂ ΔHtotal two-step path (green) = direct path (orange) MANIPULATION RULES REVERSE flip the sign of ΔH MULTIPLY scale ΔH by the same factor ADD sum the ΔH values CANCEL species on opposite sides Whatever you do to a reaction, do to its ΔH. COMBINE KNOWN STEPS A → B (ΔH₁) + B → C (ΔH₂)A → C ΔHtotal = ΔH₁ + ΔH₂ (B cancels) CED ANCHOR Enthalpy is a state function — ΔH depends only on initial and final states, not the path. So a target ΔH is built by reversing, scaling, and adding reactions of known ΔH. (ENE-3.C) AP Chemistry · Unit 6 · Thermodynamics
Hess's law follows from enthalpy being a state function: ΔH depends only on the initial and final states, not the path. So you can add known reactions — reversing one flips its ΔH sign, scaling one multiplies its ΔH — to build the target reaction and sum the ΔH values.
Path Assembler · Open the sandbox →

The traps assemble the steps without checking that they actually sum to the target, or mishandle the signs and factors when reversing and scaling. Manipulate each known reaction, confirm the steps add to the target, then add the adjusted ΔH values.

The work

3 ways in · any order
Lesson
Hess's Law

Enthalpy is a state function, so ΔH sums over any path — reverse flips the sign, scaling multiplies. The lesson assembles steps to a target and sums ΔH, then closes with a ten-scenario check.

Skill check · 10 scenarios
Diagnostic
10-item topic check

Ten items spanning the Topic 6.9 misconceptions: Hess steps assembled without checking the target, ΔH treated as fixed regardless of amount, and signs mishandled when reversing or scaling equations.

Not started · 10 items · ~15 min
Targeted Practice
Drill a single misconception

Pick one of the failure modes you missed and drill it on its own. The round is adaptive: two correct in a row clears the misconception and moves you to the next.

Take the diagnostic to identify your misconceptions