Mistake Master

Mass Spectrometry of Elements

▶︎  Watch it animatedinteractive step-through · ~3 min · optional

A mass spectrometer sorts the atoms of a sample by mass and counts how many land at each mass. Run an element through one and you get its isotopes and their relative abundances: a spectrum of peaks where position is mass and height is how common that isotope is. The periodic table's average atomic mass is built directly from that spectrum.

UNIT 1 TOPIC 1.2 • MASS SPECTROMETRY OF ELEMENTS ISOTOPE MIXER Elements are mixtures of isotopes — mass spectrometry reveals the mix. 1 ISOTOPES OF CHLORINE 2 MASS SPECTRUM 3 AVERAGE ATOMIC MASS 35Cl 17 protons 18 neutrons isotope mass 34.96885 amu relative abundance 75.8% 37Cl 17 protons 20 neutrons isotope mass 36.96590 amu relative abundance 24.2% peak height ∝ relative abundance 0 50 100 relative abundance (%) 34 35 36 37 38 mass / charge (m/z) ³⁵Cl 75.8% ³⁷Cl 24.2% WEIGHTED AVERAGE (34.96885 × 0.758) = 26.506 amu + (36.96590 × 0.242) = 8.946 amu = 35.45 amu 26.506 + 8.946 = 35.452 ≈ 35.45 PERIODIC TABLE VALUE 17 Cl 35.45 The periodic-table mass is this weighted average of the isotopes. ! CED ANCHOR Average atomic mass is the abundance-weighted mean of the isotope masses. AP Chemistry · Unit 1 · Atomic Structure & Properties
A mass spectrum reads as a set of peaks: each peak sits at an isotope's mass and rises to that isotope's relative abundance. Chlorine's two isotopes (about 76% Cl-35 and 24% Cl-37) combine by a weighted average into the 35.45 amu on the periodic table.

The one idea to hold onto is that the average atomic mass is a weighted average, not a midpoint. It is pulled toward whichever isotope is most abundant, so it usually sits nowhere near halfway between the lightest and heaviest peak.

The work

3 ways in · any order
Lesson
Mass Spectrometry

A mass spectrum encodes isotope masses and abundances as peaks. The lesson reads spectra both ways, from peaks to the weighted-average atomic mass and back, and closes with a ten-scenario check on what each peak's position and height actually mean.

Skill check · 10 scenarios
Diagnostic
10-item topic check

Ten items on reading a mass spectrum: matching peaks to isotopes, telling a peak's position (mass) from its height (abundance), and computing the weighted-average atomic mass rather than a simple midpoint.

Not started · 10 items · ~15 min
Targeted Practice
Drill a single misconception

Pick one of the failure modes you missed and drill it on its own. The round is adaptive: two correct in a row clears the misconception and moves you to the next.

Take the diagnostic to identify your misconceptions