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pH and pKa

Comparing the pH to the pKa tells you which form of a species dominates. When pH < pKa, the protonated (acid, HA) form predominates; when pH > pKa, the deprotonated (conjugate base, A⁻) form predominates; at pH = pKa, the two forms are equal. Indicators change color by this same shift between forms.

UNIT 8 TOPIC 8.7 • pH AND pKa pH VS pKa pH compared with pKa predicts the dominant form of a weak acid system. pKa − 2 pKa − 1 pH = pKa pKa + 1 pKa + 2 HA dominates equal amounts A⁻ dominates ← lower pH (more acidic) higher pH (more basic) → pH < pKa [HA] > [A⁻] HA (protonated form) dominates. pH = pKa [HA] = [A⁻] Equal amounts of HA and A⁻ present. pH > pKa [A⁻] > [HA] A⁻ (deprotonated form) dominates. pKa = −log Ka where Ka is the acid dissociation constant. CED ANCHOR pH = pKa + log [A⁻] / [HA] At pH = pKa the log term is 0, so [HA] = [A⁻]. AP Chemistry · Unit 8 · Acids and Bases
Comparing pH to pKa tells you which form dominates. When pH < pKa, the protonated (acid, HA) form predominates; when pH > pKa, the deprotonated (conjugate base, A⁻) form predominates; at pH = pKa, the two are equal. Indicators work by this same principle.
Predominant Form · Open the sandbox →

The trap misunderstands indicator behavior — an indicator is a weak acid whose two forms (different colors) predominate on either side of its pKa, so its color change signals where the pH sits relative to that pKa.

The work

3 ways in · any order
Lesson
pH and pKa

pH versus pKa decides the predominant form, and indicators work the same way. The lesson reads the predominant form and indicator behavior, then closes with a ten-scenario check.

Skill check · 10 scenarios
Diagnostic
10-item topic check

Ten items spanning the Topic 8.7 misconception: indicator behavior misunderstood — how the color-changing forms relate to pH and pKa.

Not started · 10 items · ~15 min
Targeted Practice
Drill a single misconception

Pick one of the failure modes you missed and drill it on its own. The round is adaptive: two correct in a row clears the misconception and moves you to the next.

Take the diagnostic to identify your misconceptions